- Japanese release date: December 27, 2014
- Japanese ISBN: 978-4-757545-23-6
- English release date: July 21, 2015
- English ISBN: 978-0-31630-501-3
- Cover character: Finnian
- Extras title: Black Exorcist
- 093. "The Butler, Descending" (その執事、下降, Sono Shitsuji, Kakō)
- 094. "The Butler, Exasperated" (その執事、激昂, Sono Shitsuji, Gekikō)
- 095. "The Butler, Dismayed" (その執事、失望, Sono Shitsuji, Shitsubō)
- 096. "The Butler, Encouraging" (その執事、勧奨, Sono Shitsuji, Kanshō)
- 097. "The Butler, Fascinated" (その執事、感興, Sono Shitsuji, Kankyō)
Volume 20 Gallery
The alternate cover of volume 20.
The inside cover of volume 20.
The image from the back cover of volume 20.
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